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"Acetylene, the Principles of Its Generation and Use"


EFFECT OF HEAT ON ACETYLENE.--The effect of excessive retention of heat
in an acetylene generator upon the gas itself is very marked, as
acetylene begins spontaneously to suffer change, and to be converted into
other compounds at elevated temperatures. Being a purely chemical
phenomenon, the behaviour of acetylene when exposed to heat will be fully
discussed in Chapter VI. when the properties of the gas are being
systematically dealt with. Here it will be sufficient to assume that the
character of the changes taking place is understood, and only the
practical results of those changes as affecting the various components of
an acetylene installation have to be studied. According to Lewes,
acetylene commences to "polymerise" at a temperature of about 600 deg. C.,
when it is converted into other hydrocarbons having the same percentage
composition, but containing more atoms of carbon and hydrogen in their
molecules. The formula of acetylene is C_2H_2 which means that 2 atoms of
carbon and 2 atoms of hydrogen unite to form 1 molecule of acetylene, a
body evidently containing roughly 92.3 per cent. by weight of carbon and
7.7 per cent. by weight of hydrogen.


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